No not usually, at least not that I've seen from most online stores. I like Walmart the best if they sell what I want. I've not found a cheaper price anywhere online included, even before shipping. Then you have to add in shipping when buying online. Black powder stuff is the one exception to this. It's cheaper at a few local gun shops. Bullets are cheapest at Dicks, but powder and primers are way higher than the local gun shops and Walmart.
The problem is that there is quite a bit of ammo I buy that Walmart doesn't carry. For some reason my rifle greatly prefers Federal Fusion ammo, yet Walmart doesn't sell that. So I have to buy it locally or online.
That being said If I'm going to order online imo Natchezss.com is the best. Often times they are the cheapest. Another sight to check out is Grafs Reloading Supply. They often have good prices too.