Shoot it in the ear with a .22. If you get a skunk make a dispatch pole. Put a shot in the end of it and put a smaller PVC pipe in a bigger PVC pipe. Rig a shot so it won't fall out when you push down the PVC poles. Fill the shot with 10cc's of acetone. Put the needle in the skunks lungs. If you do it slowly the skunk will die without spraying. PM me for more details.