RE: biggest to smallest.
Get a reloading manual and look through it. Usually they list the calibers smallest to largest(.17-.500). They are in inches...for example 25 caliber is .25 inches, 50cal is .5inches. then they list the different cartridges of each caliber least powerful to most. for example, the first 7mm cartridge listed would be the one they thought was the least powerful and the last would be the most powerful.