It took me a while to get my wife into hunting or even just shooting. I think the thing that helped the most is that we have a really good archery club 8 miles from home. There are a few women that shoot there. That was the step in the door. Once she started shooting she was hooked. By the time fall rolled around she was ready for the deer stand.

I took her out the first half a dozen times and sat less than 100 Yds away so that I could walk her out in the dark. Before I knew it she was out on her own. She shot a Doe her first year, that was her first shot at a deer.
Now I have to fight her to see who gets to hunt and who gets the kids......LOL.....