The de Bange obturator is used on the breech face of artillery pieces that use bag charges. It positively seals the breech from powder gases. i would like to see a machinist make a minature de Bange obturator for muzzleloader breechplugs.
http://en.wikipedia.org/wiki/Charles_Ragon_de_Bange
Many attempts had been made at developing breech-loading cannons, but the ineffectiveness of the sealing of the breech, creating loss of power and danger for the gunners, had remained a major difficulty. The technique invented by de Bange provided for a doughnut-shaped grease-impregnated
asbestos pad to be fitted at the back of the chamber, between a mushroom-shaped head and the screw-breech. When the gun was fired, the expanding gas would push the mushroom head, thereby compressing the pad and effectively sealing the chamber.