I dont know if sex is really what matters the most in deer wariness. I would say that the most important thing would be the age. I hunt in a buck only area so the doe dont have to be as careful as bucks. But on the other hand I have seen a group of two bucks and a few does stand in an open field while somebody shot and missed a buck 7 times, and the doe finally took off, and then one buck took off, but the other waited until it was chased into the woods with a truck. Anyway no matter what sex deer are going to get much smarter as they get older, because of the simple fact that they have lived longer and are more experienced.