I've shot many, many coons with the .22. Coons are tough, and like someone else said, a poorly placed shot is going to just **** them off. Well, actually a solid body shot will kill them, but not right away. A proper head shot will kill them instantly - that's what I aim for.
If you miss the brain, it can take several shots to kill a tough coon. You need to use the right kind of ammo too - high or hyper-velocity hollowpoints. If the person you're talking about had actually hit the brain, the coon would have been DRT. My guess is they missed the vitals and therefore the coon didn't die right away.
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