I don't use the store bought stuff myself, mostly because I'm cheap. I do check the bladder of every deer I kill, doe or buck. I carry two 35mm film canisters to the field with me to recover urine. They're water tight and two will usually be plenty, although I once killed a button buck that was so full of pee I just detached the bladder and tied string around the tube. It woulda never fit in those film canisters. Most deer I've killed have very little in them, though, probably because they pee from the stress of getting hit.
I cut the urine with water, 50/50 and then just use if for cover scent. If the doe was in heat, all the better.
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"Be polite. Be professional. But, have a plan to kill everyone you meet." Gen. James Mattis, USMC
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